syllabus of u.p.board xii th
paper - ii
By-MANOJ SINGH/ORIENTAL STUDY CENTRE
233/5-6, SHASTRI NAGAR, KANPUR
9415153946,9532999522
Physical chemistry
1.
Chemical Equilibrium
Reversible
reaction, Active mass, Chemical equilibrium, Law of mass action, Application of
law of mass action on different equilibria, Equilibrium Constant and its
characteristics, Relation between Kp and Kc, Factors
affecting equilibrium constant, Le-Chetelier’s
principle.
2.
Chemical Kinetics
Rate
of reaction, Collision Theory, Activation energy, Rate constant, Factors
affecting rate constant, Temperature coefficient, Molecurity of reaction, order of reaction, Types of Order of
Reaction-Zero, First, Pseudo-monomolecural
reaction, reaction constant for first order reaction, Half life for first order
reaction, Related Numericals.
3.
Ionic Equilibrium
Electrolytes (Strong and weak), Arrhenius theory of electrolytic
dissociation, Ostwald’s dilution law,
Ionic Product of Water, Theory of Acids and bases(Arrhenius theory, Lewis concept, Bronsted and Lawry concept),
Salts and their types, PH Value, Common Ion Effect, Solubility product,
Applications of Common ion effect and solubility product, Salt hydrolysis, Buffer
Solution(Acidic and Basic Buffer,), working of buffer solution Indicators- definition,
characteristics,
Ph-Range,
working of Phenolphthalein and methyl Orange-Ostwald’s theory and Quinoid Theory.
4.
Dilute Solution
Concentration
of solution-
g/l, %, Molarity, Molality, Normality and molar fraction, Colligative properties- Osmotic Pressure-
semipermeable membrane, Osmosis, exo-osmosis, endosmosis, Osmotic pressure,
Berkeley-Hartley method, Lowering of Vapour Pressure, Elevation of Boiling
Point, Depression of Freezing point, Vont Hoff’s Factor.
5.
Catalysis
Definition, Characteristics, Types- positive, negative, auto and induces catalysis, Homogeneous and
heterogeneous catalysis, Catalytic promoter
and catalytic poison, Theory of Catalysis- Intermediate compound theory and Adsorption theory.
6.
Distribution Law
Definition,
Limitations, Nernst’s equation.
7.
Colloidal State
Types of solution- True solution, Colloidal
solution, suspension, Definition of Colloidal
solution, characteristics of Colloidal
solution, Types of Colloidal solution – Lyophilic and Lyophobic, Preparation of Colloidal solutions-
dispersion methods(Colloidal mill,
Bredig arc, Peptization), Condensation method, chemical methods(double
decomposition,Hydrolysis, Oxidation, Reduction), Purification of Colloidal
solution(simple and electro-Dialysis,
Ultrafiltration), Properties of colloidal solution-Nature, Diffusibility,
Effect of gravity, Surface tension, Visibility, Optical Properties(Tyndall effect), Kinetic Property(Brownian movement),
Electrophoresis, Coagulation, Flocculation value, Proection and protective colloids, Gold Number, Application of Colloidal
solution.
8.
Thermodynamics and
Thermochemistry
System(open, closed and isolated), Boundary, surroundins, Thermodynamic
Processes(Isothermal, Adiabatic, Isochoric, Isobaric, Cyclic), Internal Energy, Enthalpy, First Law of thermodynamics, Applications
of First law of dynamics, Heat of
Reaction, Heat of Formation, Heat of combustion, Heat of Neutralization, Hess’s
law of constant heat summation and it’s applications.
Organic Chemistry
1.
Purification of
Organic Compounds
Crystallization, Sublimation, Distillation(simple, fractional, vacuum, steam distillation), chromatography.
2.
Estimation of
Organic compounds
Liebig’s method(C,H), Carius method(Cl,Br,I), Peria and schiff’s method(S,P),
Duma and Kjeldahl”s method(N).
3. Determination of Empirical, Molecular and
Structural formulae of Organic compounds
4.
Classification and
nomenclature of Organic Compounds
5.
Isomerism
Structural Isomerism(chain, position, metamerism,functional,
tautomerism, ring-chain isomerism), Stereo-Isomerism(Geometrical,
Optical)
6.
Mechanism of Organic
reactions
7.
Alkanes
General methods of preparation and general physical and chemical properties
of Alkanes, Methane, Ethane(Only reactions for the purpose of what
happens when and conversions)
8.
Alkenes
General methods of preparation and general physical and chemical properties
of Alkenes, Ethylene(Only reactions for the purpose of what
happens when and conversions)
9.
Alkynes
General methods of preparation and general physical and chemical properties
of Alkynes, Acetylene(Only reactions for the purpose of what
happens when and conversions)
10.
Petroleum
Composition of petroleum, Purification of Petrol, Cracking, Synthetic
Petrol(Fischer and Tropsch method, Bergius
method, I.C.I method), Knocking, Ant-knocking
agent, Octane Number, Flash Point, Petrochemicals .
11.
Halogen Derivatives
of Alkanes
General methods of preparation and general physical and chemical properties
of Alkyl halides, Lab/Industrial Methods of C2H5Br and CHCl3 and their physical and chemical properties.
12.
Alcohols
General methods of preparation and general physical and chemical properties
of Alcohols, Lab/Industrial Methods of CH3OH,
C2H5OH and Glycerol
and their physical and chemical properties.
13.
Ether
General methods of preparation and general physical and chemical properties
of Ethers, Lab/Industrial Methods of C2H5OC2H5
and it’s physical and chemical properties.
14.
Aldehydes and
Ketones
General methods of preparation and general physical and chemical properties
of Aldehydes and Ketones, Lab/Industrial Methods of HCHO, CH3CHO and CH3COCH3
and their physical and chemical properties.
15.
Carboxylic Acid
General methods of preparation and general physical and chemical properties
of Carboxylic acids, Lab/Industrial Methods of HCOOH and CH3COOH
and their physical and chemical properties.
16.
Derivatives of Monocarboxylic
acid
Acetyl
Chloride, Ethyl Acetate, Acetamide, Acetic anhydride
17.
Oils,Fats, Soaps
and Waxes
18.
Urea
19.
Alkyl Amine
General methods of preparation and general physical and chemical properties
of Primary amines, Lab/Industrial Methods of C2H5NH2 and It’s physical and
chemical properties.
20.
Carbohydrates
Glucose and Fructose (reactions)
21.
Food
Balanced Diet, Vitamins,
22. AROMATIC Chemistry
Lab/Industrial Methods of Preparation and physical and chemical properties of
Followings-
Benzene,
Toluene, Chlorobenzene, Phenol, Benzaldehyde, Benzoic Acid, Nitrobenzene,
Aniline.
